4.7 Article

Lifetime of dynamical heterogeneity in a highly supercooled liquid

Journal

PHYSICAL REVIEW E
Volume 82, Issue 3, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.82.030501

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We numerically examine dynamical heterogeneity in a highly supercooled three-dimensional liquid via molecular-dynamics simulations. To define the local dynamics, we consider two time intervals: tau(alpha) and tau(ngp). tau(alpha) is the alpha relaxation time, and tau(ngp) is the time at which non-Gaussian parameter of the Van Hove self-correlation function is maximized. We determine the lifetimes of the heterogeneous dynamics in these two different time intervals, tau(hetero)(tau(alpha)) and tau(hetero)(tau(ngp)), by calculating the time correlation function of the particle dynamics, i.e., the four-point correlation function. We find that the difference between tau(hetero)(tau(alpha)) and tau(hetero)(tau(ngp)) increases with decreasing temperature. At low temperatures, tau(hetero)(tau(alpha)) is considerably larger than tau(alpha), while tau(hetero)(tau(ngp)) remains comparable to tau(alpha). Thus, the lifetime of the heterogeneous dynamics depends strongly on the time interval.

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