Journal
PHYSICAL REVIEW E
Volume 78, Issue 6, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.78.061105
Keywords
electric fields; electrochemistry; liquid theory; Monte Carlo methods
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Funding
- DGAPA-UNAM PROFIP program
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We compare weak- and strong-coupling theory of counterion-mediated electrostatic interactions between two asymmetrically charged plates with extensive Monte Carlo simulations. Analytical results in both weak- and strong-coupling limits compare excellently with simulations in their respective regimes of validity. The system shows a surprisingly rich structure in terms of interactions between the surfaces as well as fundamental qualitative differences in behavior in the weak- and the strong-coupling limits.
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