Journal
PHYSICAL REVIEW B
Volume 87, Issue 1, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.87.014106
Keywords
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Funding
- Leverhulme Trust [RG66640, EP/K009702/1]
- EPSRC [EP/K009702/1, NE/B 505738/1]
- NERC [EP/K009702/1, DMR-1066158]
- NSF [EP/K009702/1, DMR-0701558, 0722625, N00014-11-1-0384, N00014-08-1-0915]
- ONR [EP/K009702/1, N00014-07-1-0825]
- EPSRC [EP/K009702/1] Funding Source: UKRI
- NERC [NE/F017081/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K009702/1] Funding Source: researchfish
- Natural Environment Research Council [NE/F017081/1, NE/B505738/1] Funding Source: researchfish
- Division Of Computer and Network Systems
- Direct For Computer & Info Scie & Enginr [0959124] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1066158] Funding Source: National Science Foundation
- Office Of The Director
- EPSCoR [0918970] Funding Source: National Science Foundation
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The dynamic properties of elastic domain walls in BaTiO3 were investigated using resonance ultrasonic spectroscopy (RUS). The sequence of phase transitions is characterized by minima in the temperature dependence of RUS resonance frequencies and changes in Q factors (resonance damping). Damping is related to the friction of mobile twin boundaries (90 degrees ferroelectric walls) and distorted polar nanoregions (PNRs) in the cubic phase. Damping is largest in the tetragonal phase of ceramic materials but very low in single crystals. Damping is also small in the low-temperature phases of the ceramic sample and slightly increases with decreasing temperature in the single crystal. The phase angle between the real and imaginary part of the dynamic response function changes drastically in the cubic and tetragonal phases and remains constant in the orthorhombic phase. Other phases show a moderate dependence of the phase angle on temperature showing systematic changes of twin microstructures. Mobile twin boundaries (or sections of twin boundaries such as kinks inside twin walls) contribute strongly to the energy dissipation of the forced oscillation while the reduction in effective modulus due to relaxing twin domains is weak. Single crystals and ceramics show strong precursor softening in the cubic phase related to polar nanoregions (PNRs). The effective modulus decreases when the transition point of the cubic-tetragonal transformation is approached from above. The precursor softening follows temperature dependence very similar to recent results from Brillouin scattering. Between the Burns temperature (approximate to 586 K) and T-c at 405 K, we found a good fit of the squared RUS frequency [similar to Delta (C-11 - C-12)] to a Vogel-Fulcher process with an activation energy of similar to 0.2 eV. Finally, some first-principles-based effective Hamiltonian computations were carried out in BaTiO3 single domains to explain some of these observations in terms of the dynamics of the soft mode and central mode. DOI: 10.1103/PhysRevB.87.014106
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