Journal
PHYSICAL REVIEW B
Volume 86, Issue 16, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.86.165210
Keywords
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Funding
- European Commission [NMP3-LA-2010-246334]
- KITP
- Materials Department, UC Santa Barbara through NSF [PH11-25915, DMR-0843934]
- Direct For Mathematical & Physical Scien [0843934] Funding Source: National Science Foundation
- Division Of Materials Research [0843934] Funding Source: National Science Foundation
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Crystalline and amorphous zinc-tin-oxide phases (c- and a-ZTO) are analyzed using density functional theory with a focus on deep subgap states, which were recently observed experimentally. Our study reveals that the broader defect band above the valence band in stoichiometric a-ZTO is due to undercoordinated single oxygen atoms whereas the narrower one below the conduction band is caused by strongly miscoordinated tin-oxygen atom complexes. Our conclusion that the deep levels above the valence band clearly originate from undercoordinated oxygen atoms is further supported by the result that hydrogen doping suppresses these levels by creating O-H bonds. This observation has also been made in experiments.
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