4.6 Article

Electric-field-driven monoclinic-to-rhombohedral transformation in Na1/2Bi1/2TiO3

Journal

PHYSICAL REVIEW B
Volume 86, Issue 13, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.86.134103

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Funding

  1. Department of Science and Technology, Government of India

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The lead free ferroelectric Na1/2Bi1/2TiO3 (NBT) is shown to exhibit electric-field-induced monoclinic (Cc) to rhombohedral (R3c) phase transformation at room temperature. This phenomenon has been analyzed both from the viewpoint of the intrinsic polarization rotation and adaptive phase models. In analogy with the morphotropic phase boundary systems, NBT seems to possess intrinsic competing ferroelectric instabilities near room temperature.

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