4.6 Article

Fully ordered Sr2CrReO6 epitaxial films: A high-temperature ferrimagnetic semiconductor

Journal

PHYSICAL REVIEW B
Volume 85, Issue 16, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.85.161201

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Funding

  1. Center for Emergent Materials at the Ohio State University, a NSF Materials Research Science and Engineering Center [DMR-0820414]
  2. Direct For Mathematical & Physical Scien
  3. Division Of Materials Research [820414] Funding Source: National Science Foundation

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We report growth of Sr2CrReO6 epitaxial films with 99% Cr/Re ordering and crystalline perfection comparable to those of high-quality semiconductor films. The Sr2CrReO6 films show a Curie temperature of 508 K and a saturation magnetization of 1.29 mu B per formula unit, which confirms the presence of strong spin-orbit coupling. Unexpectedly, electrical transport and optical absorption measurements indicate that Sr2CrReO6 is a semiconductor with a band gap of 0.21 eV. The unique combination of high temperature ferrimagnetism and semiconductivity is both scientifically interesting and highly attractive for applications.

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