Long-range atomic ordering and variable interlayer interactions in two overlapping graphene lattices with stacking misorientations

The low-energy electronic dispersion of graphene is extremely sensitive to the nearest layer interaction and thus the stacking sequence. Here, we report a method to examine the effect of stacking misorientation in bilayer graphene by transferring chemical vapor deposited (CVD) graphene onto monolithic graphene epitaxially grown on silicon carbide (SiC) (0001). The resulting hybrid bilayer graphene displays long-range Moire diffraction patterns having various misorientations even as it exhibits electron reflectivity spectra nearly identical to epitaxial bilayer graphene grown directly on SiC. These varying twist angles affect the 2D (G')-band shape of the Raman spectrum, indicating regions of both a monolayer-like single pi state and Bernal-like split pi states brought about by the differing interlayer interactions. This hybrid bilayer graphene fabricated via a transfer process therefore offers a way to systematically study the electronic properties of bilayer graphene films as a function of stacking misorientation angle.