Journal
PHYSICAL REVIEW B
Volume 85, Issue 11, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.85.115320
Keywords
-
Funding
- DARPA [N66001-10-C-4002]
- NSF [CBET 0846561]
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [846561] Funding Source: National Science Foundation
Ask authors/readers for more resources
Following the idea that there exists an optimal bandwidth for maximizing the thermoelectric figure of merit (ZT), we conduct detailed calculations in this paper to search for the optimal ZT in Bi2Te3/Sb2Te3 quantum dot (QD) nanocomposites (NCs) with Bi2Te3 QDs uniformly embedded in Sb2Te3 matrix where electron minibands are formed. The two-channel transport model, which considers both the miniband transport by the quantum-confined carriers and the background transport by the bulklike carriers, is used for electrical transport, while the lattice thermal conductivity is modeled using the modified effective medium approximation. Simultaneous decrease of the lattice thermal conductivity and the Lorenz number leads to an enhanced ZT in QD NCs when the Seebeck coefficient is not dramatically decreased. The optimal structural parameters that result in optimal electronic structure for maximizing ZT are found, with the consideration of realistic carrier scattering physics including phonon bottleneck effect. The optimal QD size is found to be similar to 6 nm, and the optimal interdot distance depends on the QD size and the doping concentration. For a given QD size, the maximum ZT is determined by the minimum of Lorenz number, which occurs when the quantum-confined carrier transport overwhelms the bulklike carrier transport.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available