Journal
PHYSICAL REVIEW B
Volume 85, Issue 1, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.85.014110
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Funding
- DARPA [54751]
- DFG [SPP 1415]
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We show how the ground state of phosphorus, black phosphorus, and the alpha-As type modification, next-lying on increasing pressure, are tightly connected over a Peierls intermediate. We unravel an intrinsic reactivity given by lone pairs, which are conserved during phase transition and are not suppressing the Peierls state. Along this line we provide a consistent solution to a classical chemical puzzle.
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