4.6 Article

Revealing the dual nature of magnetism in iron pnictides and iron chalcogenides using x-ray emission spectroscopy

Journal

PHYSICAL REVIEW B
Volume 84, Issue 10, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.84.100509

Keywords

-

Funding

  1. NSERC
  2. CFI
  3. OMRI
  4. CIfAR
  5. KOFST
  6. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences (BES) [W-31-109-ENG-38]
  7. U.S. Department of Energy [DE-AC02-98CH10886]
  8. NSFC
  9. MOST from China
  10. National Creative Research Initiative [2010-0018300]
  11. JST
  12. TRIP
  13. U.S. Department of Energy, Office of BES [DE-AC02-76SF00515]
  14. National Research Foundation of Korea [2010-0018300] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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We report a Fe K beta x-ray emission spectroscopy study of local magnetic moments in various iron-based superconductors in their paramagnetic phases. Local magnetic moments are found in all samples studied: PrFeAsO, Ba(Fe,Co)(2)As(2), LiFeAs, Fe(1+x) (Te,Se), and A(2)Fe(4)Se(5) (where A = K, Rb, and Cs). The moment size is independent of temperature or carrier concentration but varies significantly across different families. Specifically, all iron pnictide samples have local moments of about 1 mu(B)/Fe, while FeTe and K(2)Fe(4)Se(5) families have much larger local moments of similar to 2 mu(B)/Fe and similar to 3.3 mu(B)/Fe, respectively. Our results illustrate the importance of multiorbital physics in describing magnetism of these compounds.

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