Importance of the Fermi-surface topology to the superconducting state of the electron-doped pnictide Ba(Fe1-xCox)2As2

We used angle-resolved photoemission spectroscopy and thermoelectric power to study the poorly explored, highly overdoped side of the phase diagram of Ba( Fe1-xCox)(2)As-2 high-temperature superconductor. Our data demonstrate that several Lifshitz transitions-topological changes of the Fermi surface-occur for large x. The central hole barrel changes to ellipsoids that are centered at Z at x similar to 0.11 and subsequently disappear around x similar to 0.2; changes in thermoelectric power occur at similar x values. T-c decreases and goes to zero around x similar to 0.15-between the two Lifshitz transitions. Beyond x = 0.2 the central pocket becomes electron-like and superconductivity does not exist. Our observations reveal the importance of the underlying Fermiology in electron-doped iron arsenides. We speculate that a likely necessary condition for superconductivity in these materials is the presence of the central hole pockets rather than nesting between central and corner pockets.