Journal
PHYSICAL REVIEW B
Volume 83, Issue 16, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.83.165121
Keywords
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Funding
- Deutsche Forschungsgemeinschaft [1346]
- Julich BlueGene/P Grant [JIFF41]
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The identification of electronic states and the analysis of their evolution with n is key to understanding n-layered ruthenates. To this end, we combine polarization-dependent O 1s x-ray absorption spectroscopy, high-purity Srn+1RunO3n+1 (n = 1,2,3) single crystals, and ab initio and many-body calculations. We find that the energy splitting between the empty x(2) - y(2) and 3z(2) - 1 state is considerably smaller than previously suggested and that, remarkably, Sr bands are essential to understanding the spectra. At low energy, we identify the main difference among the materials with a substantial rearrangement of t(2g) orbital occupations with increasing n. This rearrangement is controlled by the interplay of Coulomb repulsion, dimensionality, and changes in the t(2g) crystal field.
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