Journal
PHYSICAL REVIEW B
Volume 84, Issue 13, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.84.132202
Keywords
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Funding
- Swedish Research Council (V.R.)
- Carl Tryggers Foundation
- Magnus Bergvall Foundation
- Natural Science Foundation of China [10974121]
- National Basic Research Program of China [2006CB806000]
- European Community [226716]
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Resonant inelastic x-ray scattering spectra excited at the O1s(-1)pi* resonance of liquid acetone are presented. Scattering to the electronic ground state shows a resolved vibrational progression where the dominant contribution is due to the C-O stretching mode, thus demonstrating a unique sensitivity of the method to the local potential energy surface in complex molecular systems. For scattering to electronically excited states, soft vibrational modes and, to a smaller extent, intermolecular interactions give a broadening, which blurs the vibrational fine structure. It is predicted that environmental broadening is dominant in aqueous acetone.
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