Journal
PHYSICAL REVIEW B
Volume 81, Issue 14, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.81.144126
Keywords
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Funding
- Spanish MCYT [MAT2007-65990-C03-01/03, CSD2007-00045]
- Vicerrectorado de Innovacion y Desarrollo, UPV [UPV2008-0020]
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We have performed a theoretical and experimental study of the structural stability of terbium phosphate at high pressures. Theoretical ab initio total-energy and lattice-dynamics calculations together with x-ray diffraction experiments have allowed us to completely characterize a phase transition at similar to 9.8 GPa from the zircon to the monazite structure. Furthermore, total-energy calculations have been performed to check the relative stability of 17 candidate structures at different pressures and allow us to propose the zircon -> monazite -> scheelite -> SrUO4-type sequence of stable structures with increasing pressure. In this sequence, sixfold P coordination is attained for the SrUO4-type structure above 64 GPa. The whole sequence of transitions is discussed in association with the high-pressure structural behavior of oxides isomorphic to TbPO4.
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