Journal
PHYSICAL REVIEW B
Volume 80, Issue 17, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.80.172104
Keywords
elastic moduli; high-pressure effects; lanthanum compounds; Raman spectra; ultrasonics; vibrational modes; X-ray diffraction
Funding
- U.S. Department of Energy [DE-AC02-05CH11231]
- NSF [DMR-0605493, EAR 06-49658]
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X-ray diffraction measurements and Raman spectroscopy at room temperature document the equation of state and the frequency shifts for E-g, T-2g, and A(1g) vibrational modes of polycrystalline LaB6 under pressure. The data exhibit smooth pressure dependencies, yielding a zero-pressure isothermal bulk modulus K-0T=164(+/- 2) GPa in good accord with independent ultrasonic measurements, and show no evidence of structural or electronic phase transitions up to at least 25 GPa.
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