4.6 Article

Unusual doping dependence of superconductivity in NayFeAs

Journal

PHYSICAL REVIEW B
Volume 79, Issue 18, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.79.184516

Keywords

annealing; arsenic alloys; doping; iron alloys; sodium alloys; stoichiometry; superconducting materials; superconducting transitions

Funding

  1. T. L. L. Temple Foundation
  2. John J. and Rebecca Moores Endowment
  3. State of Texas through the Texas Center for Superconductivity
  4. U.S. Air Force Office of Scientific Research
  5. Lawrence Berkeley Laboratory
  6. Office of Science, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering of the U.S. Department of Energy [DE-AC03-76SF00098]
  7. NSF [CHE-0616805]
  8. Robert A. Welch Foundation

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Superconductivity and phase relationships were explored in the Na-Fe-As system. The PbFCl-type 111 phase is stable only within a Na stoichiometry range of 1.00 to similar to 0.85, and exhibits bulk superconductivity within an even narrower range around 0.90 in Na0.9FeAs. In particular, stoichiometric NaFeAs is not a bulk superconductor. The onset of the superconducting transition varies in a totally different way and the highest T-c occurs in multiphase samples with a nominal composition of Na:Fe:As=0.5:1:1, where the superconductive volume-fraction is almost zero. Such doping dependency is rather surprising and in disagreement with most expectations.

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