Journal
PHYSICAL REVIEW B
Volume 79, Issue 2, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.79.024512
Keywords
barium compounds; cobalt compounds; critical points; density functional theory; electronic structure; ferromagnetic materials; iron compounds; magnetic transitions; magnetoresistance; materials preparation; nickel compounds; paramagnetic materials; proximity effect (superconductivity); renormalisation; specific heat
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We report synthesis and single-crystal measurements of magnetic, transport, and thermal properties of single crystalline BaCo2As2 as well as first-principles calculations of the electronic structure and magnetic behavior. These results show that BaCo2As2 is a highly renormalized paramagnet in proximity to a quantum critical point, presumably of ferromagnetic character and that BaFeNiAs2 behaves similarly. These results are discussed in relation to the properties of Ba(Fe,Co)(2)As-2 and Ba(Fe,Ni)(2)As-2, which are superconducting for low Co and Ni concentrations.
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