Journal
PHYSICAL REVIEW B
Volume 78, Issue 2, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.78.024521
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DC and ac magnetization, resistivity, specific-heat, and neutron-diffraction data reveal that stoichiometric LaFePO is metallic and non-superconducting above T=0.35 K, with gamma=12.5 mJ/mol K-2. Neutron-diffraction data at room temperature and T=10 K are well described by the stoichiometric, tetragonal ZrCuSiAs structure, and show no signs of structural distortions or long-range magnetic ordering to an estimated detectability limit of 0.07 mu(B)/Fe. We propose a model based on the shape of the iron-pnictide tetrahedron that explains the differences between LaFePO and LaFeAsO, the parent compound of the recently discovered high-Tc oxyarsenides, which, in contrast, shows both structural and spin-density wave transitions.
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