4.6 Article

Single-photon multiple ionization forming double vacancies in the 2p subshell of argon

Journal

PHYSICAL REVIEW A
Volume 87, Issue 4, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.87.043409

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Funding

  1. Swedish Research Council (VR)
  2. Goran Gustafsson Foundation (UU/KTH)
  3. Knut and Alice Wallenberg Foundation, Sweden
  4. European Community-Research Infrastructure Action under the FP6 Structuring the European Research AreaProgramme (through the Integrated Infrastructure Initiative Integrating Activity on Synchrotron and Free Electron Laser Science) [R II 3-CT-2004-506008]

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Single-photon ionization leading to two vacancies in the 2p subshell of argon is investigated experimentally using the photoelectron time-of-flight magnetic bottle coincidence technique. Three peaks corresponding to the P-3, D-1, and S-1 states of the dication are found in the ionization energy range 535 to 562 eV. Multiconfigurational Dirac-Fock calculations were performed to estimate the single-photon double-ionization cross sections. Reasonable agreement between the measured and simulated spectra is found if single and double excitations are taken into account in the wave-function expansion. DOI: 10.1103/PhysRevA.87.043409

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