Journal
PHYSICAL REVIEW A
Volume 82, Issue 6, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.82.060701
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Funding
- Russian Foundation for Basic Research [10-03-00807-a]
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The quantum reprojection method within the standard adiabatic Born-Oppenheimer approach is derived for multielectron collision systems. The method takes nonvanishing asymptotic nonadiabatic couplings into account and distinguishes asymptotic currents in molecular-state channels and in atomic-state channels. The method is demonstrated for the example of low-energy inelastic Li + Na collisions for which the conventional application of the standard adiabatic Born-Oppenheimer approach fails and leads to paradoxes such as infinite inelastic cross sections.
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