Journal
PHYSICAL REVIEW A
Volume 81, Issue 2, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.81.022506
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- Chemical Sciences, Geosciences, and Bioscience Division of the Office of Basic Energy Sciences, Office of Science, US Department of Energy
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Binding energies of 23 Rydberg fine-structure levels of Ni with n = 9 and L >= 5 were measured using resonant excitation Stark ionization spectroscopy. From this spectrum, the quadrupole moment and the scalar and tensor dipole polarizability of the D-2(5/2) ground state of Ni+ were determined to be Q = -0.474(2), alpha(d,0) = 7.92(6), and alpha(d,2) = 1.15(14) a.u. The electric hexadecapole moment was determined to be -0.33(21) a.u.
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