4.6 Article

Single-photon core-valence double ionization of molecular oxygen

Journal

PHYSICAL REVIEW A
Volume 78, Issue 2, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.78.023409

Keywords

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Funding

  1. Swedish Research Council (VR)
  2. Goran Gustafsson Foundation (UU/KTH)
  3. Knut and Alice Wallenberg Foundation
  4. Wenner-Gren Foundation, Sweden
  5. Leverhulme Trust
  6. AlbaNova Research Centre in Stockholm
  7. Angstrom Laboratory in Uppsala
  8. BESSY, Berlin
  9. European Community - Research Infrastructure Action under the FP6 Structuring the European Research Area Programme [R II 3-CT-2004-506008]

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Single-photon core-valence double ionization of molecular oxygen has been studied using a magnetic bottle time-of-flight electron coincidence spectrometer. The K-1V-1 double ionization electron spectrum of O-2 is reported and is assigned with the aid of ab initio calculations. A direct comparison of the core-valence double ionization electron spectra with the conventional valence band photoelectron spectrum is made. The lowest core-valence double ionization energy is found to be 571.6 eV and is associated with a (3)Pi dicationic state.

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