4.6 Article

Vibrational spectroscopy of H2+:: Hyperfine structure of two-photon transitions

Journal

PHYSICAL REVIEW A
Volume 77, Issue 6, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.77.063410

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We present the computation of two-photon transition spectra between rovibrational states of the H-2(+) molecular ion, including the effects of hyperfine structure and excitation polarization. The reduced two-photon matrix elements are obtained by means of a variational method. We discuss the implications of our results for high-resolution spectroscopy of H-2(+).

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