Evaporation of trapped anions studied with a 22-pole ion trap in tandem time-of-flight configuration

We have recently shown [J. Mikosch et al., Phys. Rev. Lett. 98, 223001 (2007)] that the storage time of a thermal ensemble of ions in a multipole radiofrequency (rf) ion trap is ultimately limited by ion evaporation. An analysis of the evaporation rate was used to determine an effective trap depth as a function of the rf amplitude. This revealed that already for moderate rf amplitudes and low average stability parameter eta the loss of ions is driven by nonadiabatic motion of the fastest ions in the rf field. Here we present the details of the experimental procedure together with our experimental apparatus, which combines a 22-pole rf ion trap with tandem time-of-flight mass spectrometry for ion selection and product analysis. We furthermore describe in detail the numerical and analytical models used in the interpretation of our results, which allows one to predict the most favorable trapping conditions in multipole rf ion traps. From a fit to our data we obtain a maximal value of the multipole stability parameter of eta(max)=0.36 +/- 0.02 for adiabatic ion motion.