Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 16, Issue 36, Pages 19130-19136Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp02345e
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H2SO4 formation from the reaction CH2OO + SO2 has been measured as a function of the water vapour concentration for close to atmospheric conditions. Second-order kinetics with regard to water indicates a preferred reaction of CH2OO with the water dimer. The obtained kinetic parameters lead to the conclusion that the atmospheric fate of CH2OO is dominated by the reaction with water vapour. A comparison with results from CH3CHOO and (CH3)(2)COO indicates a structure dependent reactivity of stabilized Criegee intermediates.
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