Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 16, Issue 22, Pages 10837-10843Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp00209a
Keywords
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Funding
- National Science Foundation of China [51203091, 60907013, 61377026]
- Liaoning Province Doctor Startup Fund [20131084]
- Open Project of the State Key Laboratory of Supramolecular Structure and Materials [sklssm201423]
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Two isomers of 4,4'-bis(1-phenyl-phenanthro[9,10-d]-imidazol-2-yl)biphenyl (BPPI), L-BPPI and Z-BPPI were prepared by tuning the substituted position on the biphenyl from para-to meta-coupling. Because of the conjugated degree change at the C2-position in the phenanthroimidazole block, the fluorescent color of L-BPPI (433 nm) and Z-BPPI (402 nm) showed an obvious blue-shift compared with that of BPPI (468 nm) in the films. Meanwhile, their non-doped devices exhibited more valuable and stable deep-blue emissions with a CIE coordinate of (0.16, 0.10) and (0.16, 0.11), respectively. Furthermore, some valuable information on structure-properties was obtained by density functional theory calculations, and photophysical and electrochemical characterization.
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