Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 16, Issue 5, Pages 1704-1718Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp52842a
Keywords
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Funding
- Natural Environment Research Council, U.K.
- Division of Chemical Sciences, Geosciences, and Biosciences, the Office of Basic Energy Sciences, U.S. Department of Energy
- National Nuclear Security Administration [DE-AC04-94-AL85000]
- Institute for Advanced Studies of the University of Bristol
- Natural Environment Research Council [NE/G01972X/1, NE/J009008/1, NE/K005316/1, NE/K004905/1, NE/I014381/1, NE/K01501X/1] Funding Source: researchfish
- NERC [NE/I014381/1, NE/K01501X/1, NE/K005316/1, NE/K004905/1, NE/G01972X/1, NE/J009008/1] Funding Source: UKRI
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The chemistry of carbonyl oxides, known as Criegee intermediates, is central to many aspects of tropospheric chemistry. For decades it has been known that these reactive species, whose electronic structure contains zwitterionic and biradical character, are formed in the ozonolysis of alkenes. However it is only recently that direct measurements of their reaction kinetics have become possible. In this perspective we describe the most recent progress in understanding the reactivity of these historically elusive molecules, explore the atmospheric chemistry implications of new experimental discoveries, and propose important new areas for investigation.
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