4.6 Article

Delayed electron-hole pair recombination in iron(III)-oxo metal-organic frameworks

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 16, Issue 11, Pages 5044-5047

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp55028a

Keywords

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Funding

  1. Fonds voor Wetenschappelijk Onderzoek [G0402.09, G0413.10, G0697.11, G0197.11, 1.5.051.13N]
  2. KU Leuven Research Fund [GOA 2011/03, OT/12/059]
  3. Flemish government [CASAS METH/08/04]
  4. Federal Science Policy of Belgium [IAP-VII/05]

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The photodynamic properties of a series of Fe(III)-MOFs have been examined via redox reactions with N,N,N',N'-tetramethyl-p-phenylenediamine as an electron donor and methyl viologen as an electron acceptor. Furthermore, photogeneration of long-lived species in MIL-88B(Fe) has been proven via transient absorption spectroscopy.

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