Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 16, Issue 9, Pages 4275-4283Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp53641f
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Funding
- Institute of Materials Research and Engineering (IMRE)
- Agency for Science, Technology and Research (A*STAR)
- Visiting Investigator Program (VIP)
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In this paper, we have synthesized two novel diketopyrrolopyrrole (DPP) based donor-acceptor (D-A) copolymers poly{3,6-dithiophene-2-yl-2,5-di(2-octyl)-pyrrolo[3,4-c]pyrrole-1,4-dione-alt-1,5-bis(dodecyloxy)naphthalene} (PDPPT-NAP) and poly{3,6-dithiophene-2-yl-2,5-di(2-butyldecyl)-pyrrolo[3,4-c]pyrrole-1,4-dione-alt-2-dodecyl-2H-benzo[d][1,2,3]triazole} (PDPPT-BTRZ) via direct arylation organometallic coupling. Both copolymers contain a common electron withdrawing DPP building block which is combined with electron donating alkoxy naphthalene and electron withdrawing alkyl-triazole comonomers. The number average molecular weight (M-n) determined by gel permeation chromatography (GPC) for polymer PDPPT-NAP is around 23400 g mol(-1) whereas for polymer PDPPT-BTRZ it is 18600 g mol(-1). The solid state absorption spectra of these copolymers show a wide range of absorption from 400 nm to 1000 nm with optical band gaps calculated from absorption cut off values in the range of 1.45-1.30 eV. The HOMO values determined for PDPPT-NAP and PDPPT-BTRZ copolymers from photoelectron spectroscopy in air (PESA) data are 5.15 eV and 5.25 eV respectively. These polymers exhibit promising p-channel and ambipolar behaviour when used as an active layer in organic thin-film transistor (OTFT) devices. The highest hole mobility measured for polymer PDPPT-NAP is around 0.0046 cm(2) V-1 s(-1) whereas the best ambipolar performance was calculated for PDPPT-BTRZ with a hole and electron mobility of 0.01 cm(2) V-1 s(-1) and 0.006 cm(2) V-1 s(-1).
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