Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 16, Issue 23, Pages 11168-11172Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp00811a
Keywords
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Funding
- National Natural Science Foundation of China [50872016, 20973033, 51125009]
- National Natural Science Foundation for Creative Research Group [21221061]
- Chinese Academy of Sciences
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An ex situ observation was made by XRD patterns, SEM and TEM images, as well as cyclic voltammogram curves of CuO/Cu integrated anodes for lithium ion batteries. For the first time, the existence of a Cu+ ion long-range transfer path was identified at the potential widow of 1.30-1.60 V during both charging and discharging processes. Both SEM and TEM images show that these nanowires networks hanging CuO nanoparticles provide a Cu+ diffusion path within our designed CuO/Cu integrated anode. This work provides new insights into the conversion reaction of inorganic anode materials, and can favor the development of high-performance conversion anodes for lithium-ion batteries.
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