4.6 Article

Interfacial charge separation in Cu2O/RuOx as a visible light driven CO2 reduction catalyst

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 16, Issue 13, Pages 5922-5926

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp00102h

Keywords

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Funding

  1. EPSRC [EP/H046380/1]
  2. ERC
  3. Spanish Ministry of Education [EX2010-0479]
  4. European Commission Marie Curie CIG [PhotoCO2]
  5. Spanish Ministry of Education
  6. University of Valencia
  7. EU for the Erasmus scholarship
  8. EPSRC [EP/K039946/1, EP/K006851/1] Funding Source: UKRI
  9. Engineering and Physical Sciences Research Council [EP/K039946/1, EP/H046380/1, EP/K006851/1] Funding Source: researchfish

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We employ transient absorption spectroscopy to record the absorption spectrum of photogenerated charge carriers in Cu2O. We have found that CO2 reduction in Cu2O is limited by fast electron-hole recombination. The deposition of RuOx nanoparticles on Cu2O results in a twofold increased yield of long-lived electrons, indicating partially reduced electron-hole recombination losses. This observation correlates with an approximately sixfold increase in the yield of CO2 reduction to CO.

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