4.6 Article

CH2OO Criegee biradical yields following photolysis of CH2I2 in O-2

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 15, Issue 44, Pages 19119-19124

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp52466c

Keywords

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Funding

  1. National Centre for Atmospheric Science (NCAS)
  2. Engineering and Physical Sciences Research Council (EPSRC) [EP/J010871/1]
  3. Engineering and Physical Sciences Research Council [EP/J010871/1] Funding Source: researchfish
  4. Natural Environment Research Council [ncas10006] Funding Source: researchfish
  5. EPSRC [EP/J010871/1] Funding Source: UKRI
  6. NERC [ncas10006] Funding Source: UKRI

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Yields of CH2OO and CH2IO2 from the reaction of CH2I radicals with O-2 are reported as a function of total pressure, [N-2] and [O-2] at T = 295 K using three complementary methods. Results from the three methods are similar, with no observed additional dependence on [O-2]. The CH2I + O-2 reaction has a yield of similar to 18% CH2OO at atmospheric pressure.

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