Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 15, Issue 26, Pages 10722-10725Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp51320c
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For the very first time, Zn-67, Sn-119 and Cu-65 NMR investigations have been carried out on Cu2ZnSnS4 derivatives (CZTS) for photovoltaic applications. NMR spectroscopy is shown to be sensitive enough to probe the Cu/Zn disorder within the kesterite structure of the studied compounds. In addition, reference spectra of Cu2ZnSnS4 are provided, and experimental Zn-67 and Cu-65 parameters are compared with ab initio calculations.
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