4.6 Article

Electrochemical performance of a graphene nanosheets anode in a high voltage lithium-ion cell

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 15, Issue 47, Pages 20444-20446

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp53718h

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Funding

  1. Ministerio de Ciencia e Innovacion [MAT2008-03160, MAT2011-27110]
  2. Junta de Andalucia [FQM-175]
  3. Regione Lazio
  4. Universidad de Cordoba

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We demonstrate the feasibility of a lithium ion battery (LIB) using graphene nanosheets (GNS) as the anode in combination with a LiNi0.5Mn1.5O4 (LNMO) high voltage, spinel-structure cathode. The GNS anode is characterized by a reversible capacity of the order of 600 mA h g(-1) and a working voltage of around 0.9 V, while the 4.8-V cathode has a theoretical capacity of 146.7 mA h g(-1). The full GNS/LiNi0.5Mn1.5O4 cell has an average working voltage of about 3.75 V and a capacity of the order of 100 mA h g(-1). The findings of this paper suggest that the graphene may be proposed as a suitable anode for application in lithium ion batteries.

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