4.6 Article

Catalytic activity of NiMnO3 for visible light-driven and electrochemical water oxidation

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 15, Issue 44, Pages 19125-19128

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp53518e

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Funding

  1. MEXT (Japan) [24350069, 25600025]
  2. NRF/MEST (Korea) through GRL [2010-00353]
  3. JSPS
  4. NRF/MEST (Korea) through WCU [R31-2008-000-10010-0]

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NiMnO3 was found to be an efficient catalyst for light-driven water oxidation using [Ru(bpy)(3)](2+) and S2O82- as a photosensitiser and a sacrificial oxidant, respectively. NiMnO3 exhibited remarkably high catalytic activity in comparison with manganese oxides and nickel oxide. For electrochemical water oxidation, the highest catalytic current was also obtained with NiMnO3 among the manganese oxides.

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