Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 15, Issue 46, Pages 20161-20169Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp53402b
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Funding
- National Science Foundation [DMR-0908781, OCI-0821527]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1310258] Funding Source: National Science Foundation
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Polymers of intrinsic microporosity (PIMs) are a promising alternative in gas separation applications; however, their industrial applicability is greatly reduced by their susceptibility toward sorption-induced plasticization. In this study, the effects of swelling during nitrogen adsorption isotherms at 77 K for five PIMs (PIM-1, PIM-1c, PIM-SBF, PIM-SBF-Me, and sPIM-1) were examined through predictive molecular simulations. The structural changes and adsorptive implications of swelling each PIM from 0 to 15% were analyzed by generating swollen snapshots of the PIM during the swelling process by means of an effective swelling procedure. The size of the free volume elements increased with the simulated swelling percentage, while the closely packed polymer chains remained associated. By comparing the simulated swollen and available experimental isotherms, this investigation shows that the amount of swelling observed during low-temperature nitrogen adsorption is strongly correlated with the interaction strength of the polymer matrix. Therefore, this study provides further support that PIMs should be designed with functionalities to increase the associative interactions of adjacent polymer chains while simultaneously prohibiting efficient packing to construct a gas separation membrane with limited low-temperature N-2 swelling and high free volumes.
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