4.6 Article

A hierarchical three-dimensional NiCo2O4 nanowire array/carbon cloth as an air electrode for nonaqueous Li-air batteries

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 15, Issue 38, Pages 15806-15810

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp52773e

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Funding

  1. 973 Program of China [2011CB933300]
  2. Science & Technology Commission of Shanghai Municipality [08DZ2270500, 11JC1400500]

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A 3D NiCo2O4 nanowire array/carbon cloth (NCONW/CC) was employed as the cathode for Li-air batteries with a non-aqueous electrolyte. After its discharge, novel porous ball-like Li2O2 was found to be deposited on the tip of NiCo2O4 nanowires. The special structure of Li2O2 and active sites of catalysts are also discussed.

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