Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 15, Issue 39, Pages 16463-16467Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp52596a
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Funding
- Region Provence-Alpes-Cote d'Azur
- ANR Bioenergie
- Direction Generale de l'Armement (DGA)
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We report the effect of UV-Vis light on the membrane-bound [Ni-Fe] hydrogenase from Aquifex aeolicus under turnover conditions. Using electrochemistry, we show a potential dependent light sensitivity and propose that a light-induced structural change of the [Ni-Fe] active site is related to an enhanced reactivation of the hydrogenase under illumination at high potentials.
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