4.6 Article

Manipulating spin hyper-polarization by means of adiabatic switching of a spin-locking RF-field

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 15, Issue 34, Pages 14248-14255

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp52061g

Keywords

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Funding

  1. Russian Foundation for Basic Research [12-03-31042, 12-03-33082, 12-03-31775, 13-03-00437]
  2. Alexander von Humboldt Foundation
  3. Russian Government [11.G34.31.0045]

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We propose a technique for transferring the multiplet spin polarization (CIDNP or PHIP, or one created by any other method), which is the mutual entanglement of spins, into net hyper-polarization with respect to the direction of a high magnetic field by slowly (adiabatically) switching-off a strong external RF-field with a specially selected frequency. The net hyper-polarized molecules can then be used in NMR spectroscopy or imaging for strong signal enhancement.

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