4.6 Article

Exploiting electron storage in TiO2 nanoparticles for dark reduction of As(v) by accumulated electrons

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 15, Issue 25, Pages 10335-10338

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cp51349a

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UV irradiation of an ethanolic sol of TiO2 nanoparticles produces a trapped Ti(III) centre and a noticeable Burstein shift. Direct evidence that the accumulated charges can drive the otherwise forbidden reduction of As(v) by conduction band electrons is presented.

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