Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 14, Issue 1, Pages 76-81Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cp22700a
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Funding
- Catalysis for Sustainable Energy'' (CASE) research initiative
- Danish Ministry of Science, Technology and Innovation
- Danish National Research Foundation
- Lundbeck Foundation
- Air Force Office of Scientific Research [FA9550-10-1-0572]
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This communication examines the effect of the surface morphology of polycrystalline copper on electroreduction of CO2. We find that a copper nanoparticle covered electrode shows better selectivity towards hydrocarbons compared with the two other studied surfaces, an electropolished copper electrode and an argon sputtered copper electrode. Density functional theory calculations provide insight into the surface morphology effect.
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