4.6 Article

A comparative study on Na2MnPO4F and Li2MnPO4F for rechargeable battery cathodes

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 14, Issue 10, Pages 3299-3303

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cp40082k

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Funding

  1. Ministry of Knowledge Economy, Republic of Korea [20112020100070]
  2. Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning (KETEP)
  3. Korea government Ministry of Knowledge Economy [20114010203120]
  4. KISTI [KSC-2010-C200006]

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Electrochemical properties of A(2)MnPO(4)F (A = Na/Li) were investigated both experimentally and with first principles calculations. A new Li2MnPO4F phase was successfully synthesized for the first time. A one alkali metal ion reaction occurred reversibly within a reasonable voltage window and a two alkali metal ion reaction took place at higher voltages.

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