4.6 Article

The Golden Rule. Application for fun and profit in electron transfer, energy transfer, and excited-state decay

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 14, Issue 40, Pages 13731-13745

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cp41658a

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Funding

  1. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-FG02-06ER15788]

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Time-dependent perturbation theory and application of the Golden Rule have been shown to be quantitatively applicable to electron transfer in the inverted region, energy transfer, and excited-state decay based on spectroscopic measurements on d pi(6) polypyridyl complexes of Ru(II), Os(II), and Re(I).

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