The charge transfer kinetics of the oxidation of silver and nickel nanoparticles via particle-electrode impact electrochemistry

The electro-oxidation of silver and nickel nanoparticles in aqueous solution was studied via their collisions with a carbon electrode. The average charge passed per impact varies with electrode potential and was analysed to determine that AgNPs display an electrochemically fast (reversible) one-electron oxidation, whilst the NiNPs exhibit slow (irreversible) 2-electron kinetics. Kinetic parameters are reported.