4.6 Article

Mass transport controlled oxygen reduction at anthraquinone modified 3D-CNT electrodes with immobilized Trametes hirsuta laccase

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 14, Issue 34, Pages 11882-11885

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cp41588g

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Funding

  1. European Research Council [NMP4-SL-2009-229255]
  2. VTT, Finland
  3. Engineering and Physical Sciences Research Council [EP/D038588/1] Funding Source: researchfish
  4. EPSRC [EP/D038588/1] Funding Source: UKRI

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Carbon nanotubes covalently modified with anthraquinone were used as an electrode for the immobilization of Trametes hirsuta laccase. The adsorbed laccase is capable of oxygen reduction at a mass transport controlled rate ( up to 3.5 mA cm(-2)) in the absence of a soluble mediator. The storage and operational stability of the electrode are excellent.

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