Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 14, Issue 11, Pages 3713-3724Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cp40198c
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Funding
- JST ERATO
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This feature article focuses on the relationship between the interfacial structures constructed by molecular self-organization and the properties of organic photovoltaic devices. The use of self-assembled monolayers (SAMs) is reviewed for metal and metal oxide/organic interfaces, while surface-segregated monolayers (SSMs) are introduced as a new method for the modification of organic/organic interfaces. Research up to now has clearly demonstrated the effectiveness of the control of energy levels and other properties at the interfaces to enhance photovoltaic performance. The possibility of more precise control of the interfacial structures is also discussed.
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