Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 14, Issue 32, Pages 11273-11276Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cp41748k
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Funding
- National Science Foundation [CHE-0955242]
- GAANN fellowship
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0955242] Funding Source: National Science Foundation
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Resonance Raman spectra of poly(2-methoxy-5-(3'-7'-dimethyloctyloxy)-1,4-phenylenevinylene) (MDMO-PPV) and small molecule acceptor blend charge transfer (CT) complexes reveal long and detailed progressions of overtone and combination bands. These features are sensitive to the specific MDMO-PPV/ acceptor interactions and enable quantitative calculations of vibrational mode specific displacements of the polymer CT complex.
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