Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 13, Issue 41, Pages 18436-18446Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cp21584a
Keywords
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Funding
- Deutsche Forschungsgemeinschaft [Pu 180/6-1]
- Grant Agency of the Academy of Sciences of the Czech Republic [IAA400400504, 203/09/P306]
- Ministry of Education, Youth and Sports of the Czech Republic [MSM6046137307, LC06071]
- MEXT
- JSPS
- IMRAM
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High-resolution N 1s and O 1s photoelectron spectra (PES) of NO are presented together with spectra of the subsequent Auger decay. The PES are analyzed by taking spin-orbit splitting of the (2)Pi ground state into account providing detailed information on equilibrium distances, vibrational energies, and lifetime widths of the core-ionized states. In the Auger electron spectra (AES) transitions to five metastable dicationic final states are observed, with two of them previously unobserved. A Franck-Condon analysis of the vibrational progressions belonging to these transitions provides detailed information on the potential-energy curves of the dicationic final states as well as on the relative Auger rates. The present calculations of the potential-energy curves of NO2+ agree well with the experimental results and allow an assignment of the two hitherto unresolved Auger transitions to excited states of NO2+, C-2 Sigma(+) and c(4)Pi.
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