4.6 Article

BET specific surface area and pore structure of MOFs determined by hydrogen adsorption at 20 K

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 13, Issue 8, Pages 3220-3222

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cp01873b

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Funding

  1. European Commission DG Research [SES6-2006-518271/NESSHY]

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Low-pressure high-resolution hydrogen adsorption for the metal-organic framework MIL-101 are measured at 19.5 K and pressures below 57 kPa. The BET specific surface area and micropore volume are determined and compared to results from nitrogen adsorption at 77 K. Steps in the hydrogen adsorption isotherm are correlated to the pore structure of MIL-101.

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