Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 13, Issue 9, Pages 3645-3648Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cp02496a
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Funding
- PRIN programme [2008JKBBK4]
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The photochemical cis-trans isomerization of retinal in rhodopsin is investigated by structure sampling and excited state QM/MM trajectories with surface hopping. The calculations uncover the motions responsible for photoproduct formation and elucidate the reasons behind the efficient photoisomerization in the primary event of visual transduction.
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